Hi David,
So far, the only thing I've found that produces a satisfactory result is to eliminate the glow. The approach is to make a line stub with the desired arrowhead style, increase the linewidth as desired. Then, underlay the stub so that the arrowheads align. Group if desried. Note, initially, keeping the line color something like yellow helps visually with the alignment process. (You can also change the cap type to flat.) Export to PDF. Somewhat inconvenient work-around. Benefit: the "glow" is no longer fuzzy. Have not discovered a non-fuzzy glow.
Exporting to SVG, EMF and re-importing to Visio look OK within Visio, but look bad when subsequently saved as PDF